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Sorry but you don't seem to provide very much information, have you tried remapping the shortcut and have you downloaded the latest drivers for your tablet

What kind of Wacom tablet do you have, depending on the version you can backup your settings and try reinstalling the drivers from scratch and import the settings again.

Why do you feel the need to reset the workspace in a flash, I haven't reset my custom workspace in over 6 months and it's only a mouse click away should I need to, seems a bit strange that you would need to map something like that when you can do it with two mouse clicks which takes about 2 seconds