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i have a question regarding to pen tool usage.

i'm quite new using it and i can recognize the advantages of it.

question is: is there a way making complex shape sketch using just a paths like  curved line of the same thickness and regular line endings, and then when finished apply various brush effects (that are available in artisitic or caligraphic brushes).

i would not limit this question just on photoshop as i prefer making this in coreldraw, if possible.